Process for the preparation of a 6-halo-3-methyl-1-trialkylsilyl

Details Process for the preparation of a 6-halo-3-methyl-1-trialkylsilyl Process for the preparation of a 6-halo-3-methyl-1-trialkylsilyl

1988-10-27

1990-02-13

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 718

Patent

active

049008587

ABSTRACT:
6-halo-3-methyl-1-trialkylsilyloxy-1,3,5-hexatriene, useful as an intermediate in the preparation of terpene compounds, is prepared by reaction of a 6-halohexadienal with a halo-silane in the presence of a tertiary amine.

REFERENCES:
patent: 3472888 (1969-10-01), Bazouin
House et al., "J. of Org. Chem.", 34, No. 8 (1969), pp. 2324-2336.
The Journal of Organic Chemistry, vol. 34, No. 8, 1969, pp. 2324-2336; H. O. House et al., "The Chemistry of Carbanions, XVIII".

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