Reactivation process for iridium-containing catalysts using low

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Gas or vapor treating

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208140, 502 35, 502230, B01J 2396, B01J 2346, B01J 2364, L10G 35085

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active

044448953

ABSTRACT:
A process is described for reactivating agglomerated iridium-containing catalysts such as Pt-Ir on Al.sub.2 O.sub.3 reforming catalyst. The agglomerated catalyst is decoked to remove carbon deposits; treated with hydrogen to reduce metal oxides to the free metals; pretreated with hydrogen halide to provide at least about a 1.3 weight percent halide content; and treated with a low mass flow rate of chlorine of about one gram chlorine per 100 grams catalyst per hour. Use of a low mass halogen flow rate significantly retards ferrous metal corrosion and significantly reduces the quantity of chlorine normally used in achieving high redispersion values.

REFERENCES:
patent: 3937600 (1976-02-01), Yates et al.
patent: 3939062 (1976-02-01), Sinfelt et al.
patent: 3941682 (1976-03-01), Kmak et al.
patent: 4359400 (1982-11-01), Landolt et al.

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