Oligomerization of olefins

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585527, C07C 202

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active

044905718

ABSTRACT:
An oligomerization process is effected by treating olefinic hydrocarbons containing from 2 to about 6 carbon atoms in the presence of a catalyst comprising boron fluoride composited on an alumina support. The catalyst is treated with an additive comprising an oxygen or nitrogen-containing compound either prior to or during the process whereby the product which is obtained from the reaction will contain oligomer isomers possessing minimal branching.

REFERENCES:
patent: 3109041 (1963-10-01), Child et al.
patent: 3997621 (1976-12-01), Brennen
patent: 4048108 (1976-09-01), Ryu
patent: 4048109 (1976-09-01), Ryu
patent: 4108920 (1978-08-01), Ryu
patent: 4110410 (1978-08-01), Ryu
patent: 4308414 (1981-12-01), Madqaukar et al.

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