Process for recovering molybdenum and copper from sulfide concen

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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423 27, 423 53, 423 54, 423 61, C01G 300, C01G 3900

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044447337

ABSTRACT:
A hydrometallurgical process is provided for the recovery of molybdenum values from a molybdenum disulfide concentrate containing copper. The process comprises forming an aqueous slurry of finely divided molybdenum concentrate of carbonates and hydroxides of alkali metals, and pressure leaching the slurry in the presence of oxygen at an elevated temperature and pressure for a time sufficient to effect conversion of the contained molybdenum values to alkali metal molybdate and provide a residue containing copper oxide or basic copper carbonate from which copper is later recovered. The molybdenum values are recovered from solution by solvent extraction and the solvent thereafter stripped of the molybdenum as ammonium molybdenum using ammonium hydroxide. The molybdenum is recovered as crystals of ammonium molybdate by crystallization, e.g., by evaporating the stripping solution.

REFERENCES:
patent: 1895811 (1933-01-01), Morgan
patent: 2187750 (1940-01-01), Marvin
patent: 3576595 (1977-04-01), Chiola et al.
patent: 4298582 (1981-11-01), Menashi et al.
patent: 4320094 (1982-03-01), Menashi et al.
Dresher et al., "Journal of Metals", Jun. 1956, pp. 794-800.

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