Method of controlling the polymerization of acrylates

Details Method of controlling the polymerization of acrylates Method of controlling the polymerization of acrylates

1994-05-24

1995-03-21

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

C08F 410

Patent

active

053996410

ABSTRACT:
The present invention relates to a method of controlling the polymerization of acrylates using a catalyst which is selected from at least one of zinc, cadmium, or mercury halides in combination with free iodine to give acrylate polymers having narrow molecular weight distributions, via group transfer polymerization.

REFERENCES:
patent: 3100200 (1963-08-01), Smith
patent: 4414372 (1983-11-01), Farnham
patent: 4417034 (1983-11-01), Webster
patent: 4508880 (1985-04-01), Webster
patent: 4611037 (1986-09-01), Musch et al.
patent: 4940760 (1990-07-01), Boettcher et al.
patent: 5196491 (1993-03-01), Cho et al.
Polymer Letters vol. 9, pp. 97-102 (1971) "Preparation of Alternating Copolymers in the Presence of Metal Halides in an Aqueous Medium".
Macromolecules 1984, 17, 1415-1417.

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