Low thermal expansion coefficient polyimides with improved elong

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528125, 528128, 528172, 528173, 528174, 528176, 528183, 528185, 528188, 528190, 528191, 528220, 528229, 528350, 528353, 4284735, C08G 7310, C08G 6926, C08G 6300

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active

052604080

ABSTRACT:
Polyimide compositions, films, and electronic devices using polyimides, based on 9,9-bis(perfluoroalkyl)xanthene-2,3,6,7-tetracarboxylic dianhydride or 9-aryl-9(perfluoroalkyl)xanthene-2,3,6,7-tetracarboxylic dianhydride and 3,3',4,4'-biphenyl tetracarboxylic dianhydride or 2,2-bis(3,4-carboxyphenyl)hexafluoropropane dianhydride and benzidine derivatives which offer a combination of desirable properties including, low linear coefficient of thermal expansion, low moisture absorption, high glass transition temperature, low dielectric constant, and improved tensile elongation.

REFERENCES:
patent: 5051520 (1991-09-01), Trofimenko
patent: 5097000 (1992-03-01), Trofimenko
patent: 5115090 (1992-05-01), Sachdev et al.
"Polyimides Derived from 2,2'-Bis(trifluoromethyl)-4,4'-diaminobiphenyl.1. Synthesis and Characterization of Polyimides Prepared with 2,2'-Bis(3,4-dicarboxyphenyl)hexafluoropropane Dianhydride or Pyromellitic Dianhydride," Matsuura, et al, Macromolecules, vol. 24, No. 18, 1991, pp. 5001-5005.

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