Process for synthesizing a molecular sieve having the offretite

Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing

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423326, C01B 3328

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active

049942506

ABSTRACT:
A crystalline, gallioaluminosilicate molecular sieve having the offretite structure is synthesized by mixing a substantially gallia-free aluminosilicate hydrogel containing a templating or directing agent with a galliosilicate solultion substantially free of alumina to form a mixture and then crystallizing the resultant mixture, usually in 24 hours or less.

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patent: 4340573 (1982-07-01), Vaughan et al.
patent: 4495303 (1985-01-01), Kuehl
patent: 4521297 (1985-06-01), Angevine et al.
patent: 4803060 (1989-02-01), Occelli
S. Hayashi, K. Suzuki, S. Shin, K. Hayamizu and O. Yamamoto, "High Resolution .sup.29 Si Nuclear Magnetic Resonance Study on Gallosilicates with Zeolitic Structures," Bull. Chem. Soc. Jpn., vol. 58, 1985, pp. 52-57.
J. M. Newsam, D. E. W. Vaughan, "Structural Studies of Gallosilicate Zeolites," New Developments in Zeolite Science and Technology, Proceedings of the 7th International Zeolite Conference, Tokyo, 1986, pp. 457-464.
U.S. Patent Application Ser. No. 904,027, "Crystalline Galliosilicate with the Offretite Structure," Occelli, filed Sep. 4, 1986.
U.S. Application Ser. No. 398,770, "Process for Synthesizing a Molecular Sieve Having the Faujasite Structure and Containing Aluminum and Gallium," Occelli, filed Aug. 25, 1989.

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