Process for the production of C.sub.1 to C.sub.4 oxygenated hydr

Details Process for the production of C.sub.1 to C.sub.4 oxygenated hydr Process for the production of C.sub.1 to C.sub.4 oxygenated hydr

1982-12-08

1985-01-08

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Group ib metal containing catalyst utilized for the...

518714, 518716, C07C 2706

Patent

active

044927738

ABSTRACT:
C.sub.1 to C.sub.4 oxygenated hydrocarbons are produced by contacting synthesis gas at a temperature in the range 150.degree. C. to 450.degree. C. and a pressure in the range of 1 to 700 bars with a catalyst comprising a supported mixture of a rhodium component and a silver component. The preferred support is silica. Other metal components which may be incorporated on the support are iron, manganese, molybdenum, tungsten, ruthenium, chromium, thorium and zirconium. Furthermore the support can be activated prior to incorporation of the metal components.

REFERENCES:
patent: 3957857 (1976-05-01), Pruett et al.
patent: 4162262 (1979-07-01), Ellgen et al.
patent: 4235798 (1980-11-01), Bartley et al.
Bhasin et al., J. of Catalysis, 54, 120-128, (1978).

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