Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1979-06-28
1980-11-25
Mars, Howard T.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
252460, 252471, 252474, C07C 2706
Patent
active
042357985
ABSTRACT:
A process for selectively preparing a mixture of two-carbon atom oxygenated hydrocarbons, namely, acetic acid, ethanol and acetaldehyde, by continuously contacting a gaseous reaction mixture containing hydrogen and carbon monoxide with a solid catalyst comprising rhodium in combination with one or more alkali metals selected from the group consisting of lithium, potassium, cesium and rubidium at reaction conditions correlated so as to favor the formation of a substantial proportion of such two-carbon atom products.
REFERENCES:
patent: 4116994 (1978-06-01), Vannice et al.
patent: 4154751 (1979-05-01), McVicker et al.
Bartley William J.
Ellgen Paul C.
Wilson Thomas P.
Lieberman Bernard
Mars Howard T.
Union Carbide Corporation
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