Sputtered chromium-alloy coating for plastic

Chemistry: electrical and wave energy – Processes and products – Vacuum arc discharge coating

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428457, 428462, C23C 1500, B32B 1504

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active

041315308

ABSTRACT:
A sputtering method and target for depositing a crack-resistant metal coating on plastic is described. The target consists essentially of Cr, 5 to 30% Fe and 0 to 5% scavenger elements. Al, Ce, La, Ti and Zr, among others, are preferred scavengers. ABS plastic is a preferred substrate. The coated articles have the appearance of bright chromium metal, and are useful as automotive trim.

REFERENCES:
patent: 2993806 (1961-07-01), Fisher et al.
patent: 4022947 (1977-05-01), Grubb
patent: 4028206 (1977-06-01), King
W. Slusark, et al. "Structure & Electrical Conductivity of Cosputtered Gold-Chromium Alloy Films," J. Appl. Phys., vol. 44, pp. 2891-2892 (1973).
J. A. Thornton et al, "Internal Stresses in Titanium, Nickel, Molybdenum, and Tantalum Films Deposited by Cylindrical Magnetron Sputtering, " J. Vac. Sci. Tech., vol. 14, pp.164-168 (1977).
N. Hosokawa et al, Self-Sputtering Phenomena in High-Rate Coaxial Cylindrical Magnetron Sputtering," J. Vac. Sci. Tech., vol. 14, pp. 143-146 (1977).
J. A. Thornton, "Sputter Deposition Onto Plastics," Proc. 18th Ann. Conf. of Society of Vacuum Coaters, Key Biscayne, Fla., Apr. 7-9, 1975, pp. 8-26.
J. S. Chapin, "The Planar Magnetron," Research Development, vol. 25, pp. 37-40 (1974).
N. E. Ryan, "An Appraisal of Possible Scavenger Elements for Chromium and Chromium Alloys," J. Less Common Metals, vol. 6, pp. 21-35 (1964).
F. Henderson et al., "The Effect of Nitride-Formers Upon the Ductile-Brittle Transition in Chromium," J. Inst. Metals, vol. 92, pp. 111-117 (1963-1964).

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