Process for the preparation of urethanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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Other Related Categories

560 24, 560 26, 560 27, 560 28, 560 29, 560 30, 560 31, 560 32, 560 33, 560115, 560157, 560158, 560160, 560163, 560165, C07C125065, C07C125073

Type

Patent

Status

active

Patent number

046878726

Description

ABSTRACT:
A process for preparing urethanes by reacting a solution of a nitrogen-containing organic compound and a hydroxyl-containing organic compound with carbon monoxide in the presence of a catalyst comprising rhodium, as a metal or compound, is disclosed. In the process of this invention, the rate of conversion and selectivity to urethane is increased by providing a rhodium catalyst comprising a polyamino ligand having at least two tertiary amino groups capable of coordinating with rhodium.

REFERENCES:
patent: 3338956 (1967-08-01), Mountfield
patent: 3993685 (1976-11-01), Zajacek et al.
patent: 4052437 (1977-10-01), Licke
patent: 4491670 (1985-01-01), Bhaduri et al.

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