Hydrogenation of unsaturated hydrocarbons with cyclometallated t

Details Hydrogenation of unsaturated hydrocarbons with cyclometallated t Hydrogenation of unsaturated hydrocarbons with cyclometallated t

1985-01-22

1987-02-24

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556450, 556453, 556466, 556467, 585266, 585273, 585274, 585275, 585276, C07F 1500, C07F 708, C07C 505, C07C 502

Patent

active

046458492

ABSTRACT:
A method for hydrogenating olefins and alkynes is provided wherein the unsaturated hydrocarbon is reacted under mild conditions in the presence of a cyclometallated transition metal catalyst which shows greater resistance to degradation caused by oxidation.

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J. Dehand and M. Pfeffer, "Cyclometallated Compounds", Coordination Chemistry Reviews, 18 (1976) 327-352.
Michael I. Bruce, "Cyclometalation Reactions", Angew. Chem. Int. Ed. Eng., 16 (1977) 73-86.

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