Method for preparing polybutadiene endowed with improved process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253332, 525340, 526 78, 526 86, 526142, 526164, 5263404, C08F 206, C08F 606

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049905732

ABSTRACT:
The processability of a polybutadiene with a high content of 1,4-cis-structure is improved by means of the addition of PCl.sub.3 before the polymerization reaction is quenched and when Mooney viscosity of polybutadiene has reached a prefixed value, preferably lower than, or equal to 30; the polymerization of butadiene is carried out in a solution in an aliphatic or cycloaliphatic solvent, in the presence of a catalytic system based on rare earths, preferably a neodymium-based catalytic system.

REFERENCES:
patent: 3704286 (1972-11-01), Schafer et al.
patent: 4699960 (1987-10-01), Gordini et al.
Hackh's Chem. Dict., J. Grant (ed.), McGraw-Hill, Inc., N.Y. (1969) pp. 571-572.

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