Method for acylating aminoanthraquinones

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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546262, C07C10375

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active

045979057

ABSTRACT:
A method for acylating aminoanthraquinone dyes which comprises reducing the dye to the leuco form, reacting the leuco dye with an acylating agent and oxidizing the acylated leuco compound to form the desired acylated dyes. In a preferred embodiment bis 1,4-aminoanthraquinone dyes and bis 1,5,aminoanthraquinones are formylated.

REFERENCES:
patent: 938616 (1909-11-01), Thomaschewski
patent: 938618 (1909-11-01), Deinet
patent: 957041 (1910-05-01), Deinet
patent: 2245535 (1941-06-01), Stallmann et al.
patent: 2794032 (1957-05-01), Frey
patent: 3719489 (1973-03-01), Cieciuch et al.
E. de Barry Barnett, Anthracene and Anthraquinone, pp. 212-217, 1921.
Burstall, J.C.S., Chem. Comm., No. 1, 1965, p. 15 "A Facile Transacylation Reaction in the Anthracene Series".
Setsune et al., J.C.S., Chem. Comm., 1982, pp. 1022-1023, "Synthesis and cis-to-trans Isomerization of N,N'-Diacyl Derivatives of Indigotin."

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