Process for preparing monohydrocarbyltin trihalides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 722

Type

Patent

Status

active

Patent number

041488148

Description

ABSTRACT:
A process is provided for preparing monohydrocarbyltin trihalides, RSnX.sub.3, wherein R is an alkyl, cycloalkyl, alkaryl, aryl or aralkyl group of 1-24 carbon atoms, and X is a halogen atom by the redistribution reaction between a tetrahydrocarbyltin, R.sub.4 Sn, a trihydrocarbyltin halide, R.sub.3 SnX, or a dihydrocarbyltin dihalide, R.sub.2 SnX.sub.2, and a tin tetrahalide, SnX.sub.4, in the presence of sulfonium or isothiuronium salts as catalysts.

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Price et al., Sulfur Bonding, The Ronald Press Co. N.Y., pp. 152, 153, 160, 161 (1962).
Johnson, Ylid Chemistry, Academic Press, N. Y., p. 17 (1966).
Reid, Organic Chemistry of Bivalent Sulfur, Chemical Publ. Co., N.Y., V1, pp. 32 and 33 (1958).

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