Oxidation of isobutane to tertiary butyl hydroperoxide

Details Oxidation of isobutane to tertiary butyl hydroperoxide Oxidation of isobutane to tertiary butyl hydroperoxide

1992-02-20

1992-09-22

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568564, 568569, C07C40904

Patent

active

051498855

ABSTRACT:
The present invention relates to the oxidation of isobutane to TBHP wherein the oxidation exothermic heat of reaction is removed by circulating a portion of the liquid reaction mixture through an indirect heat exchanger and comprises the further feature that the molecular oxygen necessary for the oxidation is introduced by means of sparging into the cooled, circulating liquid reaction mixture.

REFERENCES:
patent: 2845461 (1958-07-01), Winkler et al.
patent: 4263448 (1981-04-01), Leacock
patent: 4404406 (1983-09-01), Lutz et al.
patent: 4408081 (1983-10-01), Foster
patent: 4408082 (1983-10-01), Baumgarter
Winkler et al, "Ind. & Eng. Chem." vol. 53(8) pp. 655-658.

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