Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...
Patent
1998-05-06
2000-05-09
Buttner, David
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Mixing of two or more solid polymers; mixing of solid...
525130, 525131, 528 45, 528 65, 528 75, 528 85, 528 28, C08G 7104
Patent
active
06060560&
ABSTRACT:
This invention provides a process for producing a polyurethane resin from a hydrogenated polydiene diol or polyol having a functional group equivalent weight of 750 to 10000, a reinforcing agent having a functional group equivalent weight of 30 to 200, and a polyisocyanate. In a preferred embodiment, the process comprises reacting at least one of a polydiene diol or a reinforcing diol or triol with the polyisocyanate at an NCO/functional group molar ratio of 0.4 to 0.7 or a functional group/NCO molar ratio of 0.25 to 0.55 to form a stable reaction product, adding to this reaction product an additional sufficient amount of the polyisocyanate and, as needed, one or both of the polydiene diol or the reinforcing agent to bring the NCO/functional group ratio up to from 0.9 to 1.1 and to achieve a polydiene diol content of 35 to 80% w (on solids basis) and a reinforcing agent content of 2 to 17% w (on solids basis), and reacting this final mixture to form a crosslinked polyurethane product. This process can also be carried out at an OH/NCO ratio of 0.9 to 1.1 using a blocked polyisocyanate wherein the intermediate reaction product is a stable polyurethane resin.
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Buttner David
Haas Donald F.
Shell Oil Company
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