Isomerization of 2-methyl-3-butenenitrile

Details Isomerization of 2-methyl-3-butenenitrile Isomerization of 2-methyl-3-butenenitrile

1980-08-05

1981-11-03

Brust, Joseph Paul

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C12130

Patent

active

042985463

ABSTRACT:
The selectivity of isomerization of 2-methyl-3-butenenitrile to linear unconjugated pentenenitriles (e.g., 3-pentenenitrile) is increased by conducting the isomerization reaction in the presence of butadiene. The linear penetenenitrile products are useful as intermediates in the preparation of adiponitrile.

REFERENCES:
patent: 3536748 (1970-10-01), Drinkard, Jr. et al.
patent: 3542847 (1970-11-01), Drinkard, Jr. et al.
patent: 3676481 (1972-07-01), Chia
patent: 3852328 (1974-12-01), Chia et al.
patent: 3852329 (1974-12-01), Tomlinson
patent: 3853948 (1974-12-01), Drinkard, Jr. et al.

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