Polyether-containing double metal cyanide catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502154, 502159, B01J 3100

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active

055456014

ABSTRACT:
Improved double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC compound, an organic complexing agent, and from about 5 to about 80 wt. % of a polyether polyol that has tertiary hydroxyl groups. Compared with other DMC catalysts, those of the invention have excellent activity for epoxide polymerization, and they can be used to make polyols having very low unsaturation even at high epoxide polymerization temperatures.

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J. L. Schuchardt et al., Preparation of High Molecular Weight Polyols Using Double Metal Cyanide Catalylsts, "Proceedings of the SPI, 32nd Annual Polyurethane Technical/Marketing Conference", Oct. 1989, p. 360.

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