Process for producing monodispersed vinyl polymer fine particles

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525253, 525261, 525262, 525263, 525267, 525288, 525292, 525293, 525308, 525309, 526214, 526909, 526 80, C08F 226, C08F 440

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active

052199436

ABSTRACT:
A process for producing monodispersed fine particles of a vinyl polymer is disclosed, which comprises polymerizing monomers containing at least one vinyl monomer selected from the group consisting of aromatic vinyl compounds, acrylic esters, and a methacrylic ester in the presence of (1) a surface active agent represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a substituted or unsubstituted alkyl group having from 4 to 8 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted cyclohexyl group and M represents an alkali metal, (2) from 10.sup.-3 to 10.sup.-1 mol/l of a persulfate as a polymerization initiator, and (3) from 10.sup.-4 to 10.sup.-2 mol/l of a divalent metal sulfate as an electrolyte. Monodispersed vinyl polymer fine particles having a particle size of 1 .mu.m or greater with a very narrow size distribution are obtained.

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