Process for preparing alkylesters of saturated aliphatic carboxy

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260410, 2604106, 560233, C11C 302, C09F 508

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active

044811470

ABSTRACT:
Alkylesters of saturated aliphatic carboxylic acids are prepared by reacting aliphatic monoolefins containing internal double bonds and having 6 to 20 carbon atoms with carbon monoxide and an alkanol having one hydroxyl function in the presence of a catalyst of a cobalt compound and a promoter where the promoter is pyridine, a non-ortho-substituted alkylpyridine or a mixture thereof.
The monoolefins can possibly contain paraffins and the reaction is carried out with:

REFERENCES:
patent: 3883587 (1975-05-01), Isa
patent: 3935228 (1976-01-01), Keblys

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