Vinyl monomer polymerization or copolymerization catalyzed by or

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526186, 526187, 526193, 526189, 526273, 526328, 526332, 526 72, C08F 452

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active

040950174

ABSTRACT:
A catalyst system comprising (I) an organoaluminum compound, (II) an organophosphine compound, and (III) a metal salt of a beta-diketone, is effective to homopolymerize an alkene oxide, homopolymerize an ester of acrylic or methacrylic acid or certain other vinyl monomers, or to copolymerize an alkene oxide with an ester of acrylic or methacrylic acid or certain other vinyl monomers. Suitable vinyl monomers include vinyl esters, vinyl ethers, or vinyl ketones.

REFERENCES:
patent: 2924589 (1960-02-01), Jurgeleit
patent: 3180838 (1965-04-01), Chiang
patent: 3228924 (1966-01-01), Childers
patent: 3437649 (1969-04-01), Mueller
patent: 3459688 (1969-08-01), Hsieh
patent: 3468860 (1969-09-01), Hsieh
patent: 3496247 (1970-02-01), Yuguchi et al.
patent: 3553182 (1971-01-01), Mueller

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