Para-nitrodiphenylamines synthesis using Polyethers and macrocyc

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260571, 260582, C07C 8504

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041559363

ABSTRACT:
Processes for synthesizing para-nitrodiphenylamines whereby a para-halonitrobenzene is reacted with an aromatic amine selected from the group consisting of formanilides and anilines (substituted and unsubstituted) in the presence of a basic material (to remove acid) are improved by the incorporation of certain select solubilizing agents into the reaction medium. These solubilizing agents are linear, branched, or cyclic polyethers. Some of the resulting advantages are: higher reaction yield, less by-products, and a faster reaction.

REFERENCES:
Dye et al., "J. Amer. Chem. Soc.", vol. 92(17), pp. 5226-5228 (1970).
Dewald et al., "The J. Phys. Chem.", vol. 68(1), pp. 121-127 (1964).
Schwuger, "Chem. Ab.", vol. 78, Ab. No. 45399p, (1973).

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