Preparation of alkyl silanes

Details Preparation of alkyl silanes Preparation of alkyl silanes

1989-05-01

1990-11-27

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

252 496, 252 783, C07F 708

Patent

active

049737244

ABSTRACT:
A silahydrocarbon functional fliud comprising a mixture of silahydrocarbons of the formula RSiR'.sub.3, wherein the R' radicals may be alike or different, is prepared by a three step process. In the first step in a preferred embodiment, sodium, aluminum, hydrogen, and olefin (corresponding to the radical R') are reacted in the presence of a triorganoaluminum catalyst. In a second step, fresh catalyst is added and reaction is continued. In a third step, the product of the second step is reacted with a trihaloalkylsilane to produce the RSiR'.sub.3 product. Such a product satisfied the U.S. Air Force specification for silahydrocarbon base stock.

REFERENCES:
patent: 2857414 (1958-10-01), Schmidt et al.
patent: 3398171 (1968-08-01), Giraitis et al.
patent: 3480654 (1969-11-01), Sundermeyer et al.
patent: 4367343 (1983-01-01), Tamborski et al.
patent: 4595777 (1986-06-01), Bakshi et al.
patent: 4683321 (1987-07-01), Nelson
patent: 4711965 (1987-12-01), Nelson
patent: 4711966 (1987-12-01), Nelson
Tamborski et al., Ind. Eng. Chem. Prod. Res. Dev. 22, 172-178 (1983).
Synthesis & Prop. of Silahydrocarbons, a Class of Therm. Stable, Wide Liquid Range Fluids.
Ashby et al., Inorg. Chem. 2, No. 3, pp. 499-504 (1963).
Zakharkin et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 142-143 (Jan., 1966).
Gavrilenko et al., Zhurnal Obshchei Khimii 39, No. 5, pp. 1055-1058, (May, 1969).

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