Process for the preparation of substituted 2-fluoro-pyrimidines

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...

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544122, 544180, 544217, 544295, 544296, 544319, 544320, 544321, 544326, 544328, 544329, 544333, 544335, C07D23902, C07D41304, C07D40304

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056819579

ABSTRACT:
Unsubstituted or substituted 2-fluoro-pyrimidines can be prepared by reaction of the underlying 2-amino-pyrimidines with diazotization agents, mixtures of HF and H.sub.2 O containing 30-70% by weight of HF, based on the total of HF and H.sub.2 O, serving as reaction medium. The reaction medium can also contain diluents and/or inorganic salts, preferably fluorides.

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Chemical Abstracts, vol. 83, abstract No. 131545t, p. 504, (1975).
D.J. Brown, et al., J. Chem. Soc., Perkin II, pp. 204-208, (1974).
J.A. Bee, et al., J. Chem. Soc. (C), pp. 2031-2037, (1966).
Derwent Abstracts, abstract of JP 03-193,766, (1991).
Krchnak et al., Diazotisation of the Amino Group on the Pyrimidine Nucleus, Collection Czechoslov. Chem. Commun., vol. 40, pp. 1390-1395 1975.

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