2-Substituted indoles and process for their preparation

Details 2-Substituted indoles and process for their preparation 2-Substituted indoles and process for their preparation

1975-08-25

1976-10-19

Gotts, Lewis

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603191, 260558R, 260558P, 260562R, 260562A, 424274, C07D20908, C07D20912

Patent

active

039870596

ABSTRACT:
Highly branched .alpha.-substituted indoles, e.g., 2-(1-methylcyclohexyl)-indole, are prepared by treating N-(.alpha.-branched carbonyl) toluidines with alkyl lithium. The reaction sequence may be illustrated as ##SPC1##

REFERENCES:
Piozzi et al., "Chem. Abstracts," vol. 60, pp. 9232-9233, (1964).
Bradsher, "Chem. Abstracts," vol. 51, p. 6579(b), (1957).

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