Preparation of indole derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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544 94, C07D20936, C07D20942

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046110640

ABSTRACT:
Compounds which, in one of the possible tautomeric forms and as free acidic compounds, are of the general formula I ##STR1## where R is unsubstituted or substituted alkyl, alkoxy, cycloalkoxy or aryloxy and the ring A may be further substituted, are prepared by a process in which a compound of the formula II ##STR2## where X is hydrogen or an alkoxycarbonyl group and R has the above meanings with the exception of unsubstituted or substituted alkyl, is converted in an alcoholate-containing solution, and the product is then acidified.
The compounds prepared according to the invention are useful intermediates for the preparation of dyes.

REFERENCES:
patent: 3238201 (1966-03-01), Scherrer
Chemical Abstracts, vol. 102, 185098d and DD A1 213435.
Chemical Abstracts, vol. 84, 105518n & J. Org. Chem. 41, 825/31.
Chemical Abstracts, vol. 83, 147436u and J. Het. Chem., 12, 565/72.

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