Removal of chlorine-based contaminants from materials contaminat

Cleaning and liquid contact with solids – Processes – Work handled in bulk or groups

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134 26, 208262, 208390, 210639, 210644, B08B 304, B01D 1100, B01D 1300

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046107290

ABSTRACT:
The separation of a chlorine-based contaminant from a surface of a substrate covered with same is effected by dissolving the contaminant in a first solvent to form a solution thereof and admixing a further solution consisting of a membrane-like material forming component derived from mineral crude oil, bitumen or amphipathic lipids in a second solvent selected from the group consisting of halogenated hydrocarbons and p-xylene, the second solvent being miscible with the first solvent and capable of forming in the presence of water and the membrane-like material forming component an interfacial membrane-like material which has a water side and is impermeable to the contaminant. Water is then intimately contacted with the surface of the substrate so as to cause the membrane-like material to form at the surface of the substrate with the water side oriented toward the surface while the water wets the surface and spreads thereover, the membrane-like material incorporating during its formation the contaminant and mixture of solvents adjacent the surface, and the water displacing the membrane-like material away from the surface as it is being formed thereacross to thereby separate the contaminant and mixture of solvents from the surface and cover the surface with a layer of water. The invention is particularly useful for the decontamination of dioxin contaminated soils.

REFERENCES:
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patent: 4055480 (1977-10-01), Smith et al.
patent: 4057486 (1977-11-01), Meadus et al.
patent: 4217202 (1980-08-01), Paraskos et al.
patent: 4229281 (1980-10-01), Alquist et al.
patent: 4342639 (1982-08-01), Gagon
patent: 4392892 (1983-07-01), Wagner et al.
patent: 4424081 (1984-01-01), Giguere
patent: 4574013 (1986-03-01), Peterson

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