Process for thermal-activation of chalcopyrite-pyrite concentrat

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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75 1R, 75 6, 75 7, 423 23, 423 37, 423 47, 423145, 423150, 423571, 423542, 423563, 423151, C01G 312, C01G 4914

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042017483

ABSTRACT:
A process for thermal activation of chalcopyrite-pyrite ore concentrates for activation of iron values in both chalcopyrite and pyrite constituents whereby said iron values can be selectively removed in a subsequent acid leach. Controlled oxidizing conditions are maintained in an oxidizing heating zone for removal of up to about 90% of total sulfur to be removed for conversion of pyrite and chalcopyrite to their acid-leachable forms, measured by a preferable oxidation of 10 to 15% of iron in the concentrate to ferromagnetic oxides, whereby remaining total sulfur to be removed is removed in a reducing zone with the assistance of a low H.sub.2 S/(H.sub.2 +H.sub.2 S) ratio by scavenging of H.sub.2 S by said oxides.

REFERENCES:
patent: 2878102 (1959-03-01), Sternfels
patent: 3053651 (1962-09-01), McGauley
patent: 3169853 (1965-02-01), Van Es
patent: 3964901 (1976-06-01), Swinkels et al.
Swinkels et al., "The Sherritt-Cominco Process" CIM Bulletin Feb. 1978, pp. 105-108, 110, 112-114, 121, 132, 134, 136, 137.

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