Compositions: ceramic – Ceramic compositions – Carbide or oxycarbide containing
Reexamination Certificate
2001-08-20
2004-01-20
Group, Karl (Department: 1755)
Compositions: ceramic
Ceramic compositions
Carbide or oxycarbide containing
C501S089000, C501S090000, C501S091000
Reexamination Certificate
active
06680267
ABSTRACT:
BACKGROUND
1. Field
The present invention is directed to ceramic compositions and, more specifically, to a silicon carbide ceramic composition and method of making it through liquid phase sintering.
2. Related Art
Silicon carbide ceramic materials are used in a variety of applications requiring good heat resistance, strength and tribological properties. For example, silicon carbide is often used in automotive and industrial applications, such as in fluid seals. However, the limited toughness of silicon carbide has limited its utility in applications requiring this property.
Traditionally, silicon carbide is sintered by solid state sintering. Typically, solid state sintering employs boron and carbon as sintering aids. Solid state sintering is traditionally performed at about 2150° C. and yields a relatively high sintered density of about 96-98% of the theoretical density (of solid silicon carbide). The crystalline structure produced by solid state sintering, however, is undesirable for some applications. Specifically, solid state sintering results in an equiaxed crystalline microstructure with relatively low fracture toughness (approximately 2.5 MPa m
1/2
as measured by the indentation crack length method, ASTM Test No. C1421).
It has also been discovered that silicon carbide can be processed by liquid phase sintering in a manner similar to silicon nitride. Liquid phase sintering is traditionally performed at about 1750-2000° C. In liquid phase sintering, a rare earth metal oxide and alumina are typically used as sintering aids. The rare earth metal oxide and alumina form a liquid glass as the temperature is elevated during sintering. The liquid phase pulls silicon carbide particles together through capillary action. Smaller silicon carbide particles are dissolved into the glass phase and precipitate onto larger particles, densifying the material. Liquid phase sintering results in silicon carbide having elongated (acicular) crystalline microstructure. The acicular microstructure improves the fracture toughness of silicon carbide produced by liquid phase sintering over silicon carbide produced by solid state sintering by as much as two to three times (up to approximately 6 MPa m
1/2
as measured by the indentation crack length method).
Liquid phase sintering is generally performed with &bgr;-phase silicon carbide powder, which is typically more expensive than the &agr;-phase powder that may be used in the solid state sintering process. During the liquid phase sintering process, the &bgr;-phase transforms into elongated &agr;-phase grains, improving toughness. The &agr;-phase silicon carbide powder may be used in the liquid phase sintering process, but density and toughness are compromised. Where &agr;-phase silicon carbide is used in a liquid phase sintering process, higher sintering temperatures (up to about 2050° C.) and hot pressing may overcome the density and toughness problems. However, hot pressing leads to increased cost and sintering temperature that leads to a thicker reaction layer, which often must be machined off, further increasing the cost.
SUMMARY
In one embodiment, the present invention is directed to an unsintered ceramic body including a rare earth metal oxide, one of a glass phase metal oxide and a glass phase metal nitride, a boron containing compound, a free carbon containing compound and silicon carbide.
In another embodiment, the present invention is directed to a method of making a sintered ceramic body. The method includes combining a rare earth metal oxide, one of a glass phase metal oxide and a glass phase metal nitride, a boron containing compound, a free carbon containing compound, and silicon carbide to form a green ceramic. The method further includes shaping the green ceramic into a ceramic body and sintering the ceramic body.
In another embodiment, the present invention is directed to a sintered ceramic body including silicon carbide, boron, greater than about 0.1 weight percent of rare earth metal, and greater than about 0.1 weight percent of a glass phase metal.
In another embodiment, the present invention is directed to a method of sintering silicon carbide having a toughness of greater than 5 MPa m
1/2
as measured by the indentation crack length method. The method includes liquid phase sintering &agr;-phase silicon carbide at less than 2000° C. and ambient pressure.
In another embodiment, the present invention is directed to a liquid phase sintered silicon carbide material including grains, wherein at least half of the grains are 6H grain polytypes.
In another embodiment, the present invention is directed to a seal comprising a liquid phase sintered silicon carbide material including grains, wherein at least half of the grains are 6H grain polytypes.
In another embodiment, the present invention is directed to a cutting tool comprising a liquid phase sintered silicon carbide material including grains, wherein at least half of the grains are 6H grain polytypes.
In another embodiment, the present invention is directed to an armor comprising a liquid phase sintered silicon carbide material including grains, wherein at least half of the grains are 6H grain polytypes.
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patent: 5591685 (1997-01-01), Mitomo et al.
patent: 5785922 (1998-07-01), Higuchi et al.
patent: 5855841 (1999-01-01), Trigg et al.
patent: 6531423 (2003-03-01), Schwetz et al.
patent: 5-93388 (1993-04-01), None
Collins William T.
Pujari Vimal K.
Group Karl
Lowrie Lando & Anastasi, LLP
Saint-Gobain Ceramics & Plastics, Inc.
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