Polycaprolactone urethane derivatives and coating compositions t

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 292TN, 260 294R, 260 775AM, 260849, 260858, 260859R, C08G 1864, C08G 1822, C08L 7504, C08L 6132

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active

040803180

ABSTRACT:
Water insoluble urethane adducts are produced comprising the reaction product of a polycaprolactone polyol, a polyisocyanate and an anhydride of a polycarboxylic acid. The polycaprolactone polyol reacted with the polyisocyanate and the anhydride of the polycarboxylic acid has an average of at least two hydroxyl groups in the molecule, a hydroxyl number of from about 15 to about 600 and an average molecular weight of from about 290 to about 6,000. The carboxylic acid anhydride has at least one intramolecular carboxylic anhydride group. These water insoluble urethane adducts on reaction with an inorganic or organic base produce water soluble, carboxyl modified urethane oligomer addition reaction products which are eminently suitable for the production of aqueous coatings compositions. Exceptionally good coatings compositions are obtained when a crosslinker is present in the coating composition.

REFERENCES:
patent: 3186971 (1965-06-01), Hostettler et al.
patent: 3298974 (1967-01-01), Bernstein et al.
patent: 3431223 (1969-03-01), Reymore et al.
patent: 3449467 (1969-06-01), Wynstra
patent: 3459733 (1969-08-01), Byrd et al.
patent: 3639315 (1972-02-01), Rodriquez
patent: 3775354 (1973-11-01), Hostettler et al.

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